Preparation, characterization and photocatalytic performance of TiO2/CexZr1−xO2 toward the oxidation of gaseous benzene

Increasing environmental pollution caused by the volatile organic compounds due to their toxicity makes their removal imperative. So it is crucial to develop processes which can degrade these compounds effectively. The paper demonstrates that the photocatalytic activity of TiO₂ toward the decomposition of gaseous benzene in a batch reactor can be greatly enhanced by loading TiO₂ onto the surface of Ce_xZr_1−xO₂ (x ≥ 0.25) using sol-gel technology. This research investigated the relationship between x amount and the photocatalytic activity of TiO₂. The prepared photocatalysts were characterized by BET, XRD, UV-vis diffuse reflectance and XPS analyses. The specific surface area of photocatalyst decreases as x decreases. XRD results reveal the no peaks of titania were detected. Among the five catalysts prepared, only the binding energy values of Ti2p_3/2 of TiO₂/Ce_0.5Zr_0.5O₂ shift toward lower value. The order of photocatalytic activity is TiO₂/Ce_0.5Zr_0.5O₂ > TiO₂/Ce_0.75Zr_0.25O₂ > TiO₂/CeO₂ ≈ TiO₂/Ce_0.25Zr_0.75O₂ > TiO₂/ZrO₂ ≈ TiO₂. The mechanism role of Ceria-Zirconia mixed oxides in photocatalytic reaction was speculated.     

Regularity of line configurations

We show that in arithmetically-Gorenstein line arrangements with only planar singularities, each line intersects the same number of other lines. This number has an algebraic interpretation: it is the Castelnuovo–Mumford regularity of the coordinate ring of the arrangement.We also prove that every $(d?1)$-dimensional simplicial complex whose 0-th and 1-st homologies are trivial is the nerve complex of a suitable d-dimensional standard graded algebra of depth ≥3. This provides the converse of a recent result by Katzman, Lyubeznik and Zhang.     

Laplace equations,Lefschetz properties and line arrangements

In this note we extend the main result in [6] on artinian ideals failing Lefschetz properties, varieties satisfying Laplace equations and existence of suitable singular hypersurfaces. Moreover we characterize the minimal generation of ideals generated by powers of linear forms by the configuration of their dual points in the projective plane and we use this result to improve some propositions on line arrangements and Strong Lefschetz Property at range 2 in [6]. The starting point was an example in [3]. Finally we show the equivalence among failing SLP, Laplace equations and some unexpected curves introduced in [3].     

侧向局部加热对流的周期性

通过流体力学方程组的数值模拟,研究了侧向局部加热条件下Prandtl数Pr=0.0272时流体对流的周期性.结果表明:随着Grashof数Gr的增加,对流按稳态对流、单局部周期对流、双局部周期对流、准周期对流的顺序发展.当Gr<3.6×103时,对流为稳态;在3.6×103相似文献   

基于Copula的供应链金融质物组合价格风险测度研究

本文选取白银、铝和铜三种供应链金融质物作为研究对象,在分析三种质物收益率统计特征的基础上,引入Copula模型刻画供应链金融业务中质物收益率的“尖峰厚尾”特征以及质物收益率之间的非线性相关结构;采用Monte Carlo模拟方法测度考虑到极端情况下的质物组合价格风险值CVaR;利用时间平方根法则测度长周期视角下质物组合的价格风险。将CVaR与VaR测度结果进行对比,比较分析短期价格风险与长期价格风险,将Copula模型与传统风险测度方法下计算出的风险值进行对比,以期选取最优测度供应链金融质物组合长期价格风险模型。研究结果表明:从单一质物价格波动特征来看,三种单一质物的收益率均存在非正态分布和“尖峰厚尾”特征,具有一般金融资产收益率分布的特点。从模型的有效性来看,第一,CVaR比VaR能够更好地、全面地测度供应链金融质物组合的价格风险;第二,基于Copula模型的风险测度结果比传统集成风险测度结果的准确性高;第三,平方欧式距离法结果表明在五种Copula模型中,t-Copula是最优刻画供应链金融质物组合收益率间的相依关系的模型。从长短期风险测度结果来看,随着风险期限的增加,质物组合的价格风险值随之增大,以往研究中用短期风险测度往往会低估商业银行所面临的价格风险,不利于商业银行资金信贷的优化配置。得到的结论对我国商业银行开展供应链金融业务防范价格风险提供了量化支持。     

The blow-up of the conformal mean curvature flow

In this paper, we introduce and study the conformal mean curvature flow of submanifolds of higher codimension in the Euclidean space R~n. This kind of flow is a special case of a general modified mean curvature flow which is of various origination. As the main result, we prove a blow-up theorem concluding that, under the conformal mean curvature flow in R~n, the maximum of the square norm of the second fundamental form of any compact submanifold tends to infinity in finite time. Furthermore, we also prove that the external conformal forced mean curvature flow of a compact submanifold in R~n with the same pinched condition as Andrews-Baker's will be convergent to a round point in finite time.     

ChemInform Abstract: Compounds of Superatom Clusters: Preferred Structures and Significant Nonlinear Optical Properties of the BLi6X (X: F,LiF2, BeF3, BF4) Motifs.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

Telegraph Process with Elastic Boundary at the Origin

We investigate the one-dimensional telegraph random process in the presence of an elastic boundary at the origin. This process describes a finite-velocity random motion that alternates between two possible directions of motion (positive or negative). When the particle hits the origin, it is either absorbed, with probability α, or reflected upwards, with probability 1?α. In the case of exponentially distributed random times between consecutive changes of direction, we obtain the distribution of the renewal cycles and of the absorption time at the origin. This investigation is performed both in the case of motion starting from the origin and non-zero initial state. We also study the probability law of the process within a renewal cycle.     

Symplectic duality between complex domains

In this paper after extending the definition of symplectic duality [given in Di Scala and Loi (Adv Math 217:2336–2352, 2008) for bounded symmetric domains] to arbitrary complex domains of \({{\mathbb{C}}^n}\) centered at the origin we generalize some of the results proved in Di Scala and Loi (Adv Math 217:2336–2352, 2008) and Di Scala et al. (Trans Groups 13(2):283–304, 2008) to those domains.